MECHANISM OF FORMATION OF LEAD SULFIDE ULTRAFINE PARTICLES IN REVERSE MICELLAR SYSTEMS
スポンサーリンク
概要
- 論文の詳細を見る
Ultrafine PbS particles were prepared using AOT/isooctane reverse micellar systems as reaction media. On the basis of the change in UV-visible absorption spectra expressing the change in the size of semiconductor particles, the mechanism of the particle formation was studied. Because of the relatively large solubility of PbS, the growth of particles by Ostwald ripening was significant at low reactant concentration. When an excess amount of lead ion or sulfide ion was used, ultrafine PbS particles having stable spectra could be prepared. Particle coagulation was found to be controlled by the statistical distribution of particles among the reverse micelles. By irradiating a reverse micellar solution containing PbS particles stabilized by an excess amount of sulfide ion using a Xenon lamp, hydrogen was generated by the photocatalytic reduction of water.
- 社団法人 化学工学会の論文
著者
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SATO Hiroshi
Department of Cardiovascular Medicine, Osaka University Graduate School of Medicine
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HIRAI TAKAYUKI
Department of Chemical Science and Engineering, Graduate School of Engineering Science, and Research
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駒沢 勲
Department Of Chemical Science And Engineering Graduate School Of Engineering Science And Research C
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Komasawa Isao
Department Of Chemical Science And Engineering Graduate School Of Engineering Science Osaka Universi
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Hirai Takayuki
Department Of Chemical Engineering Faculty Of Engineering Science Osaka University
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Komasawa Isao
Department Of Chemical Engineering Faculty Of Engineering Science Osaka University
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TSUBAKI Yoritaka
Department of Chemical Engineering, Osaka University
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Tsubaki Yoritaka
Department Of Chemical Engineering Osaka University
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Sato Hiroshi
Department Of Anatomy And Developmental Neurobiology Institute Of Health Biosciences The University
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Sato H
Osaka Univ. Toyonaka
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